Dr. Craig P. Jasperse, Chemistry
email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J
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Minnesota State University Moorhead
Dr. Craig P. Jasperse, Chemistry email: jasperse@mnstate.edu Phone: (218) 477-2230 Office: Hagen 407J |
Online Organic
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Organic Chemistry II Chem 360online Lectures
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| Date | Streaming Videos |
mp4 Files |
Sapling | TopicCHANGE | ||
| Test 1 | Test 1 | Alcohol Reactions | Alcohol Synthesis and Reactions. Including Grignard/Organometallic Chem and Redox. | |||
| Semester-Long Notes | Complete Semester-Long Notes for Printing | |||||
| Relevant Test 1 Notes | Pre-Printable Lecture Notes that Were Used in These Test 1 Lecture Movies | |||||
| 1 | M | Jan 12 | Intro-Syllabus (69 min) |
training sessions, 10:1-9 |
1a Overview of Course, Syllabus. (69 min) (Heh heh, syllabus overview was only 13 min in face-to-face course!) 1b Jasperse personal introduction, this one (only) shows the face to go with the voice! :) 1c p1-5. Alcohol Classification and Nomenclature. (33 min) |
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| 2 | M | Jan 12 | Alcohols Lecture 2 | Pod-2 | 10:10-14 | p6-9, 15. Organometallics, Grignard Reactions; Drawing Products of Grignard Reactions, Retrosynthetic Analysis. |
| Practice Set 1 Video | Pod | General Mechanism Practice/Review and Answers and Video and Pod | ||||
| 3 | W | Jan 14 | Alcohols Lecture 3 | Pod-3 | 10:15-17 | p10-14. RMgBr Review. Ethylene Oxide (p10) RMgBr Mechanisms,including esters and epoxide (p11-13). Product prediction (p14) |
| Practice Set 2 Video | Pod | Mechanisms Problems (Test 1 Specific) and Answers | ||||
| Quiz1 | Quiz1: Grignard Reactions. Doable now; due by Test 1 | |||||
| 4 | F | Jan 16 | Alcohols Lecture 4 |
Pod-4 | 10:18-19 | p14-20. More RMgBr Synthetic Analysis, Products (14), Selectivity (12,14), Retrosynthesis (15), Synthesis Design (16). OH C=O incompatible (17). NaBH4 +LiAlH4 Reductions (18-20) |
| 5 | W | Jan 21 | Alcohols Lecture 5 | Pod-5 | 11:1-4 | p18-20, p4-5 NaBH4 +LiAlH4 Reductions. (p18-20) Alcohol reactions. OH Acid-Base(p4-5) |
| Practice Set 3 Video | Pod | Acid-Base Practice/Review -- Answers -- Movie | ||||
| 6 | F | Jan 23 | Alcohols Lecture 6 | Pod-6 | 11:5-15 | p6-10. ROH to RONa to ROR; ROH Oxidation; Oxidation-Grignard Combinations |
| 7 | M | Jan 26 | Alcohols Lecture 7 | Pod-7 | 11:16-24 | p10-16 Overview of Oxidation-Reduction chemistry; ROH -> RBr Products + Mech. to RMgBr; Retrosynthesis. |
| W | Jan 28 | Practice Set 4 Video | Pod | Retrosynthesis Problems and Answers and Video and Pod | ||
| 8 | F | Jan 30 | Alcohols Lecture 8 | Pod-8 | 11:1-34 | p16-19 Retrosynthesis, Synthesis Design and Chemical Tests, |
| 9 | M | Feb 2 | Alcohols Lecture 9 | Pod-9 | p17-19 Retrosynthesis, Chemical Tests | |
| 10 | W | Feb 4 | Alcohols Lect 10 (59 min) FIX/EDIT |
Pod-10 | p19-23 Chemical Tests, Tosylate Chemistry, SOCl2, Mechanisms Practice, Miscellaneous Practice | |
1. General Mechanism Practice/Review and Answers and Video and Pod |
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| Test 1 Preview | Pod | |||||
| Practice Test 1-Version 1 | Pod | Test1v1 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 1-Version 2 | Pod | Test1v2 with answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 1-Version 3 | Pod | Test1v3 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 1-Version 4 | Pod | Test1v4 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
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| Test 2 | Test 2 | Test 2 Spectroscopy |
Test 4 Spectroscopy: H-NMR, C-NMR, and IR | |||
| Relevant NMR notes | Pre-Printable Lecture Notes that Were Used in These NMR Lecture Movies | |||||
| Relevant NMR Problems |
Pre-Printable NMR Spectra that Were Used in These NMR Lecture Movies | |||||
| Relevant NMR Answers | Answers to the NMR Spectra that were used in These NMR Lecture Movies | |||||
| 11 | F | Feb 6 | NMR 1 | Pod-11 | Intro to NMR; H-NMR Interpretation | |
| 12 | M | Feb 9 | NMR 2 | Pod-12 | H-NMR Interpretation | |
| 13 | F | Feb 13 | NMR 3 | Pod-13 | 13:1-18 | p6-9, 14 NMR3 Overlap, Symmetry, Integration, Splitting, Spectrum Prediction |
| 14 | M | Feb 16 | NMR 4 | Pod-14 | 14:1-20 28-39 |
p10-14 H-NMRSpectrum Prediction; Chemical Shifts; Practice |
| 15 | W | Feb 18 | NMR 5 | Pod-15 | 14:21-27 | p15- Carbon NMR. |
| 16 | F | Feb 20 | NMR 6 | Pod-16 | 14:28-39 | IR, C-NMR Problems, Splitting, Problems |
| NMR Problems 1-26 | Pod | Jasperse practice problems 1-26. Practice problems in the notes that did not get covered in class for reasons of time. |
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| NMR Problems 27-42 | Pod | Jasperse practice problems 27-42. | ||||
| Test 2 Preview | ||||||
| Practice Test 2-Version 1 | Pod | Test2v1 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 2-Version 2 | Pod | Test2v2 with answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 2-Version 3 | Pod | Test2v3 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 2-Version 4 | Pod | Test2v4 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
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| Test 3 | Test 3 | Test 3: Carbonyl Chem | Test 3: Carbonyls: Addition Reactions and Enolate Reactions | |||
| Relevant Carbonyls notes | Pre-Printable Lecture Notes that Were Used in These Carbonly and Enolate Lecture Movies | |||||
| 17 | M | Feb 23 | Carbonyls Lect 1 | Pod-17 | 18:1-9 | Aldehyde and Ketone Nomenclature. H-Bonding impact on Water Solubility and Boiling Point. Review of Ketone/Aldehyde synthesis reactions we've seen before. |
| 18 | F | Feb 27 | Carbonyls Lect 2 | Pod-18 | 18:10-16 | Carbonyls Synthesis and Mechanisms for Hydrolysis of Enols, Hydrates |
| 19 | M | Mar 2 | Carbonyls Lect 3 | Pod-19 | 18:17-24 | Carbonyl Synthesis; Addition Reactions to Carbonyls |
| 20 | W | Mar 4 | Carbonyls Lect 4 | Pod-20 | 18:25-31 | Reversible Formation of Hydrates and Acetals. Addn/Elim/Substitution Reactions. Protection. |
| Practice Set 1- Movie | Pod | Mechanism Practice (Many) Test 3- - - Answers- - -Movie - - - Pod | ||||
| Quiz2 | Quiz2: Carbonyl Mechanisms, Long. Due by Test 2 | |||||
| 21 | F | Mar 6 | Carbonyls Lect 5 | Pod-21 | 18:25-50 | Acetals, Hemiacetals, Imines, Aminols, Mechanisms |
| 22 | M | Mar 9 | Carbonyls 6/Enolates 1 | Pod-22 | 18:38-50 | Aldehyde Oxidation; Chemical Tests; Imines + Mechs; Enolates (Most of class) |
| 23 | W | Mar 11 | Enolates 2 | Pod-23 | 22:1-9 | Enolates Reaction Mechanisms. Proton, Halogen, as Electrophiles |
| 24 | F | Mar 13 | Enolates 3 | Pod-24 | 22:10-16 | p16-22 Halogen Electrophiles; Polysubstitution; Iodoform; LDA vs Ox Bases; Alkyl Halide Electrophiles. |
| Practice Set 1- Movie | Pod | Mechanism Practice (Many) Test 3- - - Answers- - -Movie - - - Pod | ||||
| 25 | M | Mar 23 | Enolates 4 | Pod-25 | 22:17-27 | LDA, Ox Bases; Mono-carbonyls vs Dicarbonyls; DecarboxEnolate Review, Aldol Reaction/Condensation: Aldehydes/Ketones as Electrophiles |
| 26 | W | Mar 25 | Enolates 5 | Pod-26 | 22:24-33 | More Aldol Reactions. Aldehdyes and Ketones as Electrophiles. |
| Practice Set 1- Movie | Pod | Mechanism Practice (Many) Test 3- - - Answers- - -Movie - - - Pod | ||||
| 27 | F | Mar 27 | Enolates 6 | Pod-27 | 22:34-40 | Claisen: Ester Electrophiles. Wittig Reaction (Phosphorus Ylides) |
| 28 | M | Mar 30 | Enolates 7 | Pod-28 | 22:41-52 | Wittig Reaction and Retrosynthesis/Design |
| Practice Set 2 - Movie | Pod | Retrosynthesis Practice Test 3- - - Answers- - -Movie- - -Pod | ||||
| 29 | W | Apr 1 | Enolates Practice | Pod-29 | Retrosynthesis; Chemical Tests. (First 26 min) | |
| 1. Mechanism Practice (Many) Test 3- - - Answers- - -Movie - - - Pod 2. Retrosynthesis Practice Test 3- - - Answers- - -Movie- - -Pod Quiz2: Carbonyl Mechanisms, Long. Due by Test 2 |
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| Test 3 Preview | Pod-1 | Test Preview | ||||
| Practice Test 3-Version 1 | Pod | Test3v1 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 3-Version 2 | Pod | Test3v2 with answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Pod | Test3v3 and answers, and Movie of Jasperse Going Through it. 49 min | |||||
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| Test 4 | Test 4 | Test 4: Amines + Acids | Test 4: Amines, Carboxylic Acids, Esters, and Amides | |||
| Relevant Notes | Pre-Printable Lecture Notes that Were Used in These Amines and Acids Lecture Movies | |||||
| 29 | W | Apr 1 | Amines Lect 1 | Pod-29 | Amines 1. Nomenclature, Hybridization. Begins at 26 min into video. | |
| Practice Set 1- Movie | Pod | Acid-Base Practice/Review/Basics (Easy) -- Answers -- Movie -- Pod | ||||
| 30 | F | Apr 10 | Amines Lect 2 | Pod-30 | 1-12 | Amines 2. Properties, Basicity. Hybridization of N-lone pairs; Reactivity of Amines; Acid-Base Chemistry |
| 31 | M | Apr 13 | Amines Lect 3 | Pod-31 | 13-21 | Amines 3. Amine/Ammonium acid/base chemistry. |
| Practice Set 2- Movie | Pod | Acid-Base Practice (Harder, Test Oriented) -- Answers -- Movie -- Pod | ||||
| 32 | W | Apr 15 | Amines Lect 4 | Pod-32 | 22-27 | Amines 4. Acid-Base. Alkylation/Polyalkylation of Amines. |
| 33 | F | Apr 17 | Amines Lect 5 | Pod-33 | 28-48 | Alkylation and Amidation of Amines. Synthesis/Synthesis Design/Retrosynthesis of Amines. |
| 34 | M | Apr 20 | Amines 6-Acids Lecture 1 | Pod-34 | 1-15 | Amines 6: p32-37, 1-32min. Amine Synthesis and Synthetic Design |
| 35 | W | Apr 22 | Acids Lecture 2 |
Pod-35 | 16-23 | Acids 2. p12-19. AcidityAcid Synthesis.Hydrolysis of Acid chlorides, anhydrides, esters, and amides |
| 36 | F | Apr 24 | Acids Lecture 3 | Pod-36 | 24-39 | Acids 3. p20-25 Reactions of Acids. SOCl2, conversion to ClAvEN-O |
| Practice Set 3- Movie | Pod | Mechanisms, Retrosynthesis + Synthesis Design --- Answers --- Movie -- Pod | ||||
| 37 | M | Apr 27 | Acids Lecture 4 | Pod-37 | 40-47 | Acids 4. p26-30 ClAvEN-O interconversions, including uphill. Acid Chlorides, Anhydrides, Esters, and Amides. Synthetic interconversion. |
| 38 | W | Apr 29 | Acids Lecture 5 | Pod-38 | Acids 5. p30-36 Practice Problems in manual. | |
| 1. Acid-Base Practice (Easy) -- Answers -- Movie -- Pod 2. Acid-Base Practice (Less Easy) -- Answers -- Movie -- Pod 3. Mechanisms, Retrosynthesis + Synthesis Design --- Answers --- Movie -- Pod |
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| Test 4 Preview | Pod | 2-minute overview of what Test 4 will look like. | ||||
| Practice Test 4-Version 1 | Pod | Test4v1 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 4-Version 2 | Pod | Test4v2 with answers, and Movie of Jasperse Going Through it. 49 min | ||||
| Practice Test 4-Version 3 | Pod | Test4v3 and answers, and Movie of Jasperse Going Through it. 49 min | ||||
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| 39 | M | May 4 | Final Exam Preview and Special Topics |
| Sapling Movie |